化学刺激法提高花岗岩类岩石裂隙渗透性的实验研究

增强型地热系统(EGS)用于通过人工形成地热储层的方法从深部低渗透性岩体中开采地热能;国际上常采用水力压裂辅以化学刺激的方法改造EGS 储层以提高其渗透率。本文以采自青海共和盆地的花岗闪长岩样品为对象,选用3种不同化学刺激剂(氢氧化钠、盐酸和土酸),在3组不同注入流速条件下开展了系统化学刺激实验。结果表明:注入盐酸和土酸后样品渗透率均有提高,且采用土酸时渗透率提高幅度明显大于盐酸;但注入氢氧化钠后,样品渗透率反而降低。在3类化学刺激剂中,土酸对长石类矿物的溶蚀能力最强,而氢氧化钠溶液对石英的溶蚀能力最强,但氢氧化钠溶液在溶解岩石样品裂隙表面矿物后极易形成非定形态二氧化硅或非定形态铝硅酸盐蚀变矿物并阻塞裂隙,反而对化学刺激效果造成负面影响。总体来看,土酸是青海共和盆地干热岩体的最佳化学刺激剂。在中等注入速度(3 mL·min^-1)条件下,土酸对岩石样品的溶蚀程度就可达到最高;在此基础上进一步降低流速,则可能使溶解组分更易从液相中沉淀而充填于样品裂隙,导致样品渗透率有所下降。     

关键元素与生命健康:中国耕地缺硒吗?

地球上的生命和非生命都是由自然界已发现的92种化学元素组成的,通过全国土壤地球化学基准值与人体血液元素含量对比研究,发现血液中40~50种化学元素平均值与土壤地球化学基准值的分布高度一致,表明这些关键元素与生命息息相关。近年大家持续关注的硒(Se)元素是人体必需的微量元素,缺乏会产生健康风险,但摄入过量也会导致中毒,因此被称为健康窗口元素。过去研究认为,中国耕地缺硒是造成健康危害的原因之一。本文通过对全国3 382个网格化点位土壤采样,获得Se的地球化学基准值和空间分布数据,发现中国贫硒国土面积,按照世界卫生组织推荐值(0.1 mg/kg)和中国规范(0.125 mg/kg)计算,分别占21.1%和31.6%;适宜区(0.125~0.40 mg/kg)面积大约555万km²,占国土面积约57.1%;富硒区(>0.40 mg/kg)面积达110万km²,占国土面积约11.2%。贫硒国土主要分布在青藏高原和内蒙古局部地区,而中国9大平原的粮食主产区耕地总体上不缺硒,其中珠江三角洲平原、广西平原、成都平原、长江中下游平原是富硒区(>0.40 mg/kg),华北平原、东北平原、三江平原、关中平原是硒边缘区-适量区(0.125~0.40 mg/kg),只有河套平原是缺硒区(<0.125 mg/kg)。根据覆盖全国的网格化土壤采样分析结果,发现低硒带呈不连续的片状分布于内蒙古东部至青藏高原一带,与传统认为“低硒带分布于东北三省至西南云贵高原”不完全一致。硒的空间分布模式主要受地质背景、岩石类型、土壤类型和自然地理景观控制。     

坝上草原相关花粉源范围与相对花粉产量估算

基于坝上草原地区30个采样点表土花粉分析和植被调查的研究结果显示,花粉组合以蒿属、藜科、禾本科、菊科和莎草科等草本植物为主,基本能够反映草原植被特征,但花粉百分比与其在植被中盖度差异明显.运用Extended R-Value(ERV)模型估算的坝上草原区相关花粉源范围大致为2100m,当风速大于3.5m/s时,基本稳定,受风速影响不大.估算的相对花粉产量结果显示,蒿属和藜科的相对花粉产量最高,为禾本科的20倍左右;其次为莎草科和菊科,为禾本科的7～9倍;百合科略高于禾本科;旋花科、豆科、唇形科及委陵菜属的相对花粉产量则明显低于禾本科.利用相对花粉产量对花粉与植被关系的校正结果表明:蒿属、藜科的校正效果明显,其相对花粉产量可以作为定量重建古植被的参考;莎草科、菊科、百合科和唇形科由于受植被和花粉数据梯度限制,其相对花粉产量能否用于植被与花粉关系的校正有待通过更多植被群落调查进一步证实;其他花粉类型由于在花粉组合中含量多低于5％,所以在校正花粉与植被关系时的作用不明显.     

Late Holocene slip rate and average recurrence interval of great earthquakes on the Shangzhi segment of the Yilan‐Yitong Fault Zone,northeastern China: Constraints from paleo‐earthquakes and historical written records

The Yilan‐Yitong Fault Zone (YYFZ) is considered to be the key branch of the Tancheng‐Lujiang Fault Zone (TLFZ) in northeastern China. Although the Mesozoic and early Cenozoic deformation of the YYFZ has been studied intensively over the past century, few estimates of slip rate and recurrence interval of large earthquakes in the late Quaternary, which are the two most important parameters for understanding the potential seismic hazard of this crucial structure, were obtained. Based on integrated interpretations of high resolution satellite images and detailed geologic and geomorphic mapping, linear landforms were identified, including fault scarps and troughs, along the Shangzhi segment of the YYFZ, which exceeds 25 km in length. Synthesized results of trench excavations and differential GPS measurements of terrace surfaces indicate that two events (E1, E2) occurred along the Shangzhi segment during the late Holocene, which resulted in 3.2 ±0.1 m of total vertical co‐seismic displacement with clear features of thrust motion. ¹⁴C dating of samples suggests that event E1 occurred between 440 ±30 years BP and 180 ±30 years BP and that event E2 occurred between 4 090 ±30 years BP and 3 880 ±30 years BP, which indicates that the minimum vertical slip rate of the Shangzhi segment of the YYFZ has been approximately 0.8 ±0.03 mm/year during the late Holocene. Constraints from paleo events and the slip rate suggest that the average recurrence interval of major earthquakes on the YYFZ is 3 800 ±200 years. Historical documents in Korea show that event E1 possibly corresponds to the earthquake that occurred in AD 1810 (the Qing Dynasty in Chinese history) in the Ningguta area, which had surface‐wave magnitude (Ms) of 6.8–7.5. Studies of kinematics show that the right‐lateral strike‐slip with a reverse component has been dominant along the YYFZ during the late Holocene.     

闽中渔场的温、盐跃层分布与亚硝酸盐的层化现象

本文根据1982—1983年闽中渔场鱼类资源调查的资料,分析了本海区温、盐度跃层的强度及分布特征.结果表明:闽江口断面和平潭断面存在较强的跃层.温跃层一般出现在夏季.温跃层的强度可高达0.50℃/m,出现在牛山岛附近(水深10—20m).盐跃层一般出现在春季.盐跃层的强度可高达1.03/m,出现在闽江口白犬岛附近(水深0—10m).5月份处于丰水期,流量较大的闽江水排入海洋。由于其盐度低、比重小而浮于海水的上层,形成盐跃层现象.盐跃层最常出现的海区是在牛山岛附近.文中还探讨了闽中渔场的亚硝酸盐层化现象.3—8月,亚硝酸盐含量在水深0—20m层均较低,20m至底层含量则大幅度升高,亦出现明显的分层现象.     

福建沿海沉积物中硫化物的分布

测定了福建沿海１７９个表层沉积物样品中硫化物的含量，潮间带含量范围为２．５０—１５２．０３ｍｇ·ｋｇ－１，浅海含量范围为２．５０—２９１．９７ｍｇ·ｋｇ－１。     

福建省同安湾叶绿素的含量

根据1998年2月、5月、8月、11月对同安湾叶绿素a含量的调查,分析了同安湾叶绿素a的季节分布,并估算了初级生产力C的含量,调查结果表明春季的叶绿素a含量为全年最高,范围为2.68 μg/L～16.24 μg/L,平均值为7.22 μg/L,初级生产力C平均为4286.4mg/m2.d;夏季叶绿素a含量为1.03μg/L～5.40 μg/L,平均值为.3.34 μg/L;秋季叶绿素a含量为0.36 μg/L～1.50 μg/L,平均值为0.87μg/L,初级生产力C平均为32.84mg/mg.d;冬季叶绿素a含量为1.11μg/L～2.21μg/L,平均值为1.56 μg/L.本文还将此次调查结果与历史资料作了比较.     

分支河流体系河网形态演变规律——以格尔木河流扇为例

为了探索分支河流体系河网分布规律,为创建储层建模训练图像提供知识库信息。利用Google Earth、Global Mapper、91卫图助手等现代地理信息软件,系统测量了现代格尔木河流扇表面河道分叉特征,应用Horton定律和分形方法建立了河流扇的河网形态模型。结果表明：①格尔木河流扇从顶点到入湖段共识别出26级河道,882个节点和2162个河道段,泉线上、下的河道表现出不同的河网形态;②泉线上部共发育64个节点,每级河道数目增长是上一级河道的RB=1.8900倍,每级河道平均长度是下一级河道的RL=1.0095倍,即河网形态特征参数RB=1.8900和RL=1.0095;泉线下部共发育818个节点,每级河道数目增长是上一级河道的RB=1.0279倍,每级河道平均长度是下一级河道的RL=0.9899倍,即河网形态特征参数是RB=1.0279和RL=0.9899;③河网形态特征参数受坡度影响变化较大,坡度较大则河网形态特征参数较大,坡度较小则河网形态特征参数较小。河网形态特征参数定量表征促进了分支河流体系沉积学发展,为开展陆相盆地储层建模和砂体预测提供了新的知识库信息     

Pollen assemblages and their environmental implications in the Qaidam Basin,NW China

The Qaidam Basin is one of the most sensitive areas to climate change in China, owing to its unique geographical position and ecological condition. In this study, 32 surface‐soil pollen samples were collected to reveal the relationship between modern pollen assemblages, vegetation and precipitation in the eastern region of the Qaidam Basin. The results show that Chenopodiaceae (3.8–87%, average 48%), Artemisia (1.7–64.2%, average 17.5%) and Ephedra (0–90%, average 16.3%) are the dominant pollen types in all samples, and that different pollen assemblages correspond to different vegetation types. DCA and CCA of major pollen types demonstrate that precipitation is an important factor in the control of the distribution of vegetation in the study area. The content and concentration of the three major pollen types (Artemisia, Chenopodiaceae and Ephedra) change with the mean annual precipitation, and the optimum mean annual precipitation for Ephedra, Chenopodiaceae and Artemisia is <80, 80–200 and >160 mm, respectively. Correlation analysis between the variation in grain size of the three major pollen types and the main environmental variables shows that the grain size of the three pollen types is positively correlated with precipitation in the Qaidam Basin. The results confirm that precipitation is the most important environmental factor in the Qaidam Basin, and that it has an important effect on pollen grain size in the study area.     

济南张夏组灰岩岩溶地下水供水潜力探讨

济南南部广布巨厚张夏组灰岩,其中赋存优质丰富的岩溶地下水。出露众多泉水,其流量为800～8000m3/d。该文通过简述济南地区张夏组灰岩岩溶地下水的赋存条件与水文地质特征,概略计算与评价其资源量,论证开发利用这一新水源的可行性,以期为济南供水与保泉开辟新途径。